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Reagentless Oxidative Folding of Disulfide-Rich Peptides is Catalyzed by an Intramolecular Diselenide

In cysteine-rich peptides, diselenides can be used as a proxy for disulfide bridges, since the energetic preference for diselenide bonding over mixed selenium-sulfur bonds simplifies folding. Herein we report that an intramolecular diselenide bond efficiently catalyzes the oxidative folding of selen...

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Autors principals: Steiner, Andrew M., Woycechowsky, Kenneth J., Olivera, Baldomero M., Bulaj, Grzegorz
Format: Artigo
Idioma:Inglês
Publicat: 2012
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3365648/
https://ncbi.nlm.nih.gov/pubmed/22454362
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201200062
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