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Proximal Ligand Electron Donation and Reactivity of the Cytochrome P450 Ferric-Peroxo Anion
CYP125 from Mycobacterium tuberculosis catalyzes sequential oxidation of the cholesterol side-chain terminal methyl group to the alcohol, aldehyde, and finally acid. Here, we demonstrate that CYP125 simultaneously catalyzes the formation of five other products, all of which result from deformylation...
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| Autors principals: | , , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3329582/ https://ncbi.nlm.nih.gov/pubmed/22444582 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211499q |
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