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Proximal Ligand Electron Donation and Reactivity of the Cytochrome P450 Ferric-Peroxo Anion
CYP125 from Mycobacterium tuberculosis catalyzes sequential oxidation of the cholesterol side-chain terminal methyl group to the alcohol, aldehyde, and finally acid. Here, we demonstrate that CYP125 simultaneously catalyzes the formation of five other products, all of which result from deformylation...
Tallennettuna:
| Päätekijät: | , , , , , , |
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| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2012
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3329582/ https://ncbi.nlm.nih.gov/pubmed/22444582 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211499q |
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