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Structural control of cytochrome P450-catalyzed ω-hydroxylation

The regiospecific or preferential ω-hydroxylation of hydrocarbon chains is thermodynamically disfavored because the ease of C-H bond hydroxylation depends on the bond strength, and the primary C-H bond of a terminal methyl group is stronger than the secondary or tertiary C-H bond adjacent to it. The...

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Autori principali: Johnston, Jonathan B., Ouellet, Hugues, Podust, Larissa M., Ortiz de Montellano, Paul R.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2010
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2997901/
https://ncbi.nlm.nih.gov/pubmed/20727847
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.abb.2010.08.011
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