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Structural control of cytochrome P450-catalyzed ω-hydroxylation
The regiospecific or preferential ω-hydroxylation of hydrocarbon chains is thermodynamically disfavored because the ease of C-H bond hydroxylation depends on the bond strength, and the primary C-H bond of a terminal methyl group is stronger than the secondary or tertiary C-H bond adjacent to it. The...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2997901/ https://ncbi.nlm.nih.gov/pubmed/20727847 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.abb.2010.08.011 |
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