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In Situ Assembly of Octahedral Fe(II) Complexes for the Enantiomeric Excess Determination of Chiral Amines Using CD spectroscopy
A method for discriminating between α-chiral primary amine enantiomers is reported. The method utilizes circular dichroism spectroscopy and a sensing ensemble composed of 2-formyl-3-hydroxyl pyridine (4) and Fe(II)(TfO)(2). Aldehyde 4 reacts rapidly with chiral amines to form chiral imines, which co...
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| 主要な著者: | , , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2012
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3329375/ https://ncbi.nlm.nih.gov/pubmed/22272943 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211768v |
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