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QM/MM Studies of Hairpin Ribozyme Self-Cleavage Suggest the Feasibility of Multiple Competing Reaction Mechanisms

The hairpin ribozyme is a prominent member of small ribozymes since it does not require metal ions to achieve catalysis. Guanine 8 (G8) and adenine 38 (A38) have been identified as key participants in self-cleavage and -ligation. We have carried out hybrid quantum-mechanical/molecular mechanical (QM...

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Autori principali: Mlýnský, Vojtěch, Banáš, Pavel, Walter, Nils G., Šponer, Jiří, Otyepka, Michal
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3223549/
https://ncbi.nlm.nih.gov/pubmed/22014231
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp206963g
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