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Alkyl-metal and aryl-metal bond chemistry in coordinately unsaturated polynuclear metal complexes

A new class of coordinately unsaturated polynuclear rhodium and iridium alkyl, benzyl, and aryl derivatives of the form [RM(1,5-cyclooctadiene)](x) have been prepared by the reaction of the organolithium reagent with the cyclooctadienemetal chlorides at -78°C. The x-ray crystal structure of [μ-CH(3)...

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Publicado en:Proc Natl Acad Sci U S A
Autores principales: Schmidt, G. F., Muetterties, E. L., Beno, M. A., Williams, Jack M.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 1981
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Acceso en línea:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC319119/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592987/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.78.3.1318
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