Alkyl-metal and aryl-metal bond chemistry in coordinately unsaturated polynuclear metal complexes
A new class of coordinately unsaturated polynuclear rhodium and iridium alkyl, benzyl, and aryl derivatives of the form [RM(1,5-cyclooctadiene)](x) have been prepared by the reaction of the organolithium reagent with the cyclooctadienemetal chlorides at -78°C. The x-ray crystal structure of [μ-CH(3)...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Principais autores: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
1981
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC319119/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592987/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.78.3.1318 |
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