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Alkyl-metal and aryl-metal bond chemistry in coordinately unsaturated polynuclear metal complexes

A new class of coordinately unsaturated polynuclear rhodium and iridium alkyl, benzyl, and aryl derivatives of the form [RM(1,5-cyclooctadiene)](x) have been prepared by the reaction of the organolithium reagent with the cyclooctadienemetal chlorides at -78°C. The x-ray crystal structure of [μ-CH(3)...

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Autors principals: Schmidt, G. F., Muetterties, E. L., Beno, M. A., Williams, Jack M.
Format: Artigo
Idioma:Inglês
Publicat: 1981
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC319119/
https://ncbi.nlm.nih.gov/pubmed/16592987
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