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Chemistry of low-valent molybdenum phosphite complexes: Models of seven-coordinate reaction intermediates
A simple synthesis of the zerovalent complex Mo[P(OCH(3))(3)](6) has been devised from a potassium reduction of MoCl(4)(tetrahydrofuran)(2) followed by reaction with trimethyl phosphite at 70°. Protonation of this octahedral complex gave only low yields of the expected seven-coordinate hydride, HMo[...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
1978
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC411405/ https://ncbi.nlm.nih.gov/pubmed/16592505 |
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