Chemistry of low-valent molybdenum phosphite complexes: Models of seven-coordinate reaction intermediates
A simple synthesis of the zerovalent complex Mo[P(OCH(3))(3)](6) has been devised from a potassium reduction of MoCl(4)(tetrahydrofuran)(2) followed by reaction with trimethyl phosphite at 70°. Protonation of this octahedral complex gave only low yields of the expected seven-coordinate hydride, HMo[...
Gorde:
| Argitaratua izan da: | Proc Natl Acad Sci U S A |
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| Egile Nagusiak: | , , , , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
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National Academy of Sciences
1978
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC411405/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592505/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.75.3.1056 |
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