Chemistry of low-valent molybdenum phosphite complexes: Models of seven-coordinate reaction intermediates

A simple synthesis of the zerovalent complex Mo[P(OCH(3))(3)](6) has been devised from a potassium reduction of MoCl(4)(tetrahydrofuran)(2) followed by reaction with trimethyl phosphite at 70°. Protonation of this octahedral complex gave only low yields of the expected seven-coordinate hydride, HMo[...

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Publicado en:	Proc Natl Acad Sci U S A
Autores principales:	Muetterties, E. L., Kirner, J. F., Evans, W. J., Watson, P. L., Abdel-Meguid, S., Tavanaiepour, I., Day, V. W.
Formato:	Artigo
Lenguaje:	Inglês
Publicado:	National Academy of Sciences 1978
Materias:	Physical Sciences: Chemistry
Acceso en línea:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC411405/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592505/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.75.3.1056
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