Alkyl-metal and aryl-metal bond chemistry in coordinately unsaturated polynuclear metal complexes

A new class of coordinately unsaturated polynuclear rhodium and iridium alkyl, benzyl, and aryl derivatives of the form [RM(1,5-cyclooctadiene)](x) have been prepared by the reaction of the organolithium reagent with the cyclooctadienemetal chlorides at -78°C. The x-ray crystal structure of [μ-CH(3)...

Disgrifiad llawn

Manylion Llyfryddiaeth

Cyhoeddwyd yn:	Proc Natl Acad Sci U S A
Prif Awduron:	Schmidt, G. F., Muetterties, E. L., Beno, M. A., Williams, Jack M.
Fformat:	Artigo
Iaith:	Inglês
Cyhoeddwyd:	National Academy of Sciences 1981
Pynciau:	Physical Sciences: Chemistry
Mynediad Ar-lein:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC319119/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592987/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.78.3.1318
Tagiau:	Ychwanegu Tag Dim Tagiau, Byddwch y cyntaf i dagio'r cofnod hwn!