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Alkyl-metal and aryl-metal bond chemistry in coordinately unsaturated polynuclear metal complexes
A new class of coordinately unsaturated polynuclear rhodium and iridium alkyl, benzyl, and aryl derivatives of the form [RM(1,5-cyclooctadiene)](x) have been prepared by the reaction of the organolithium reagent with the cyclooctadienemetal chlorides at -78°C. The x-ray crystal structure of [μ-CH(3)...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
1981
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC319119/ https://ncbi.nlm.nih.gov/pubmed/16592987 |
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