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Influence of Thiolate Ligands on Reductive N–O Bond Activation. Probing the O(2)(−) Binding Site of a Biomimetic SOR Analogue, and Examining the Proton-Dependent Reduction of Nitrite
Nitric oxide (NO) is frequently used to probe the substrate–binding site of “spectroscopically silent” non-heme Fe(2+) sites of metalloenzymes, such as superoxide reductase (SOR). Herein we use NO to probe the superoxide binding site of our thiolate–ligated biomimetic SOR model [Fe(II)(S(Me2)N(4)(tr...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3178331/ https://ncbi.nlm.nih.gov/pubmed/21207999 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja107551u |
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