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Torsional Steering Controls the Stereoselectivity of Epoxidation in the Guanacastepene A Synthesis
[Image: see text] The stereoselectivity of the key epoxidation step in the synthesis of Guanacastepene A is shown to be controlled by torsional steering. In this particular epoxidation reaction, the transition structure energetic difference is enhanced by the great asynchronicity of the forming C-O...
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| Hlavní autoři: | , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2006
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3164362/ https://ncbi.nlm.nih.gov/pubmed/16597098 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol052862g |
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