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Steric Control of α- and β-Alkylation of Azulenone Intermediates in a Guanacastepene A Synthesis

The origins of different stereoselectivities observed experimentally in the alkylations of azulenone precursors in the guanacastepene A synthesis have been determined through density functional theory investigations. The optimized transition structures of methylation of two different guanacastepene...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Wang, Hao, Michalak, Karol, Michalak, Michał, Jiménez-Osés, Gonzalo, Wicha, J., Houk, K. N.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2010
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC2813942/
https://ncbi.nlm.nih.gov/pubmed/20039618
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo902283a
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