Loading...
Mechanism and Origins of Regio- and Enantioselectivities in Rh(I)-Catalyzed Hydrogenative Couplings of 1,3-Diynes and Activated Carbonyl Partners: Intervention of a Cumulene Intermediate
The mechanism of the rhodium-catalyzed reductive coupling of 1,3-diynes and vicinal dicarbonyl compounds employing H(2) as reductant was investigated by density functional theory. Oxidative coupling through 1,4-addition of the Rh(I)-bound dicarbonyl to the conjugated diyne via a seven-membered cycli...
Na minha lista:
| Main Authors: | , , |
|---|---|
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2011
|
| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3159924/ https://ncbi.nlm.nih.gov/pubmed/21365696 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201002741 |
| Tags: |
Tilføj Tag
Ingen Tags, Vær først til at tagge denne postø!
|