S K-edge XAS and DFT Studies of High and Low Spin {FeNO}(7) Thiolate Complexes: Exchange Stabilization of Electron Delocalization in {FeNO}(7) and {FeO(2)}(8)

S K-edge XAS is a direct experimental probe of metal ion electronic structure as the pre-edge energy reflects its oxidation state, and the energy splitting pattern of the pre-edge transitions reflects its spin state. The combination of sulfur K-edge XAS and DFT calculations indicates that the electr...

Full description

Saved in:
Bibliographic Details
Main Authors: Sun, Ning, Liu, Lei V., Dey, Abhishek, Villar-Acevedo, Gloria, Kovacs, Julie A., Darensbourg, Marcetta Y., Hodgson, Keith O., Hedman, Britt, Solomon, Edward I.
Format: Artigo
Language:Inglês
Published: 2010
Subjects:
Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3130116/
https://ncbi.nlm.nih.gov/pubmed/21158471
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic1006378
Tags: Add Tag
No Tags, Be the first to tag this record!

Similar Items