A carregar...
Sulfur K-edge XAS and DFT Studies on Ni(II) Complexes with Oxidized Thiolate Ligands: Implications for the Roles of Oxidized Thiolates in the Active Sites of Fe and Co Nitrile Hydratase
S K-edge XAS data on a series of Ni(II) complexes with thiolate (RS(−)) and oxidized thiolate (RSO(2)(−)) ligands are used to quantify Ni-S bond covalency and its change upon ligand oxidation. Analyses of these results using geometry optimized DFT calculations suggest that the Ni-S σ bonds do not we...
Na minha lista:
| Main Authors: | , , , , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2565589/ https://ncbi.nlm.nih.gov/pubmed/17500514 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic070244l |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|