Φορτώνει......
S K-edge XAS and DFT Calculations on Square Planar Ni(II)-thiolate Complexes: Effects of Active and Passive H-bonding
S K-edge XAS for a low-spin Ni(II)-thiolate complex shows a 0.2 eV shift to higher pre-edge energy but no change in Ni-S bond covalency upon H-bonding. This is different from the H-bonding effect we observed in high spin Fe(III)-thiolate complexes where there is a significant decrease in Fe-S bond c...
Αποθηκεύτηκε σε:
| Κύριοι συγγραφείς: | , , , , , , , |
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| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2007
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2536514/ https://ncbi.nlm.nih.gov/pubmed/17949080 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic7006292 |
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