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Highly Diastereoselective Chelation-controlled Additions to α-Silyloxy Ketones
The polar Felkin-Anh, Cornforth, and Cram-chelation models predict that the addition of organometallic reagents to silyl–protected α–hydroxy ketones proceeds via a non-chelation pathway to give anti-diol addition products. This prediction has held true for the vast majority of additions reported in...
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| 主要な著者: | , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2011
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3112462/ https://ncbi.nlm.nih.gov/pubmed/21534530 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja201629d |
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