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Alkenes as Chelating Groups in Diastereoselective Additions of Organometallics to Ketones
[Image: see text] Alkenes have been discovered to be chelating groups to Zn(II), enforcing highly stereoselective additions of organozincs to β,γ-unsaturated ketones. (1)H NMR studies and DFT calculations provide support for this surprising chelation mode. The results expand the range of coordinatin...
Wedi'i Gadw mewn:
| Prif Awduron: | , , , , |
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| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
American Chemical Society
2014
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| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4195513/ https://ncbi.nlm.nih.gov/pubmed/25328269 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om5007006 |
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