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Application of the diastereoselective photodeconjugation of α,β-unsaturated esters to the synthesis of gymnastatin H
The asymmetric synthesis of gymnastatin H has been achieved by using the photoisomerisation of a conjugated ester to its β,γ-unsaturated isomer through the protonation of a in situ generated dienol as key step. Thanks to diacetone D-glucose used as a chiral alkoxy group, the protonation occurred wel...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Beilstein-Institut
2011
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3064449/ https://ncbi.nlm.nih.gov/pubmed/21448437 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.21 |
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