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Application of the diastereoselective photodeconjugation of α,β-unsaturated esters to the synthesis of gymnastatin H

The asymmetric synthesis of gymnastatin H has been achieved by using the photoisomerisation of a conjugated ester to its β,γ-unsaturated isomer through the protonation of a in situ generated dienol as key step. Thanks to diacetone D-glucose used as a chiral alkoxy group, the protonation occurred wel...

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Bibliografiske detaljer
Main Authors: Raffier, Ludovic, Piva, Olivier
Format: Artigo
Sprog:Inglês
Udgivet: Beilstein-Institut 2011
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3064449/
https://ncbi.nlm.nih.gov/pubmed/21448437
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.21
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