A carregar...

Application of the diastereoselective photodeconjugation of α,β-unsaturated esters to the synthesis of gymnastatin H

The asymmetric synthesis of gymnastatin H has been achieved by using the photoisomerisation of a conjugated ester to its β,γ-unsaturated isomer through the protonation of a in situ generated dienol as key step. Thanks to diacetone D-glucose used as a chiral alkoxy group, the protonation occurred wel...

ver descrição completa

Na minha lista:
Detalhes bibliográficos
Main Authors: Raffier, Ludovic, Piva, Olivier
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3064449/
https://ncbi.nlm.nih.gov/pubmed/21448437
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.21
Tags: Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!