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Mechanistic Studies of the Radical SAM Enzyme DesII: EPR Characterization of a Radical Intermediate Generated During Its Catalyzed Dehydrogenation of TDP-D-Quinovose
DesII, a radical SAM enzyme from Streptomyces venezuelae, catalyzes the deamination of TDP-4-amino-4,6- dideoxy-D-glucose to TDP-3-keto-4,6-dideoxy-D-glucose in the desosamine biosynthetic pathway. DesII can also catalyze the dehydrogenation of TDP-D-quinovose to the corresponding 3-keto sugar. Simi...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3099232/ https://ncbi.nlm.nih.gov/pubmed/21513273 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja201212f |
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