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Kinetic Isolation and Characterization of the Radical Rearrangement Step in Coenzyme B(12)-Dependent Ethanolamine Ammonia-Lyase
The transient decay reaction kinetics of the 1,1,2,2-(2)H(4)-aminoethanol generated Co(II)-substrate radical pair catalytic intermediate in ethanolamine ammonia-lyase (EAL) from Salmonella typhimurium have been measured by using time-resolved, full-spectrum X-band continuous-wave electron paramagnet...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3078532/ https://ncbi.nlm.nih.gov/pubmed/20578695 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja907769g |
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