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Reaction of the Co(II)-Substrate Radical Pair Catalytic Intermediate in Coenzyme B(12)-Dependent Ethanolamine Ammonia-Lyase in Frozen Aqueous Solution from 190 to 217 K

The decay kinetics of the aminoethanol-generated Co(II)-substrate radical pair catalytic intermediate in ethanolamine ammonia-lyase from Salmonella typhimurium have been measured on timescales of <10(5) s in frozen aqueous solution from 190 to 217 K. X-band continuous-wave electron paramagnetic r...

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Detalhes bibliográficos
Main Authors: Zhu, Chen, Warncke, Kurt
Formato: Artigo
Idioma:Inglês
Publicado em: The Biophysical Society 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2599855/
https://ncbi.nlm.nih.gov/pubmed/18805934
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1529/biophysj.108.138081
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