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Photolysis of Adenosylcobalamin and Radical Pair Recombination in Ethanolamine Ammonia-Lyase Probed on the Micro- to Millisecond Time Scale by using Time-Resolved Optical Absorption Spectroscopy

The quantum yield and kinetics of decay of cob(II)alamin formed by pulsed-laser photolysis of adenosylcobalamin (AdoCbl) in coenzyme B(12) (AdoCbl)-dependent ethanolamine ammonia-lyase (EAL) from Salmonella typhimurium have been studied on the 10(-7) - 10(-1) s time scale at 295 K by using transient...

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Detalhes bibliográficos
Main Authors: Robertson, Wesley D., Warncke, Kurt
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2642536/
https://ncbi.nlm.nih.gov/pubmed/19072291
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi801659e
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