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Product and Mechanistic Analysis of the Reactivity of a C6-Pyrimidine Radical in RNA
Nucleobase radicals are the major reactive intermediates produced when hydroxyl radical reacts with nucleic acids. 5,6-Dihydrouridin-6-yl radical (1) was independently generated from a ketone precursor via Norrish Type I photocleavage in a dinucleotide, single stranded, and double stranded RNA. This...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3071645/ https://ncbi.nlm.nih.gov/pubmed/21391681 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja200317w |
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