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Silylene-mediated Polarity Reversal of Dienoates: Additions of Dienoates to Aldehydes at the δ-Position to form trans-Dioxasilacyclononenes

Silylene transfer to α,β,γ,δ-unsaturated carbonyl compounds produced oxasilacyclopentenes that underwent thermal additions to aldehydes to produce trans-dioxasilacyclononenes as single stereoisomers. This reaction, which converts the δ-position the unsaturated carbonyl compound into a nucleophilic c...

詳細記述

保存先:
書誌詳細
主要な著者: Ventocilla, Christian C., Woerpel, K. A.
フォーマット: Artigo
言語:Inglês
出版事項: 2010
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3070190/
https://ncbi.nlm.nih.gov/pubmed/21166421
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja109631z
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