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Silylene-mediated Polarity Reversal of Dienoates: Additions of Dienoates to Aldehydes at the δ-Position to form trans-Dioxasilacyclononenes
Silylene transfer to α,β,γ,δ-unsaturated carbonyl compounds produced oxasilacyclopentenes that underwent thermal additions to aldehydes to produce trans-dioxasilacyclononenes as single stereoisomers. This reaction, which converts the δ-position the unsaturated carbonyl compound into a nucleophilic c...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3070190/ https://ncbi.nlm.nih.gov/pubmed/21166421 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja109631z |
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