Sulfur versus Iron Oxidation in an Iron-Thiolate Model Complex

In the absence of base, the reaction of [Fe(II)(TMCS)]PF(6) (1, TMCS = 1-(2-mercaptoethyl)-4,8,11-trimethyl-1,4,8,11-tetraazacyclotetradecane) with peracid in methanol at −20 °C did not yield the oxoiron(IV) complex (2, [Fe(IV)(O)(TMCS)]PF(6)), as previously observed in the presence of strong base (...

Descripció completa

Guardat en:
Dades bibliogràfiques
Autors principals: McDonald, Aidan R., Bukowski, Michael R., Farquhar, Erik R., Jackson, Timothy A., Koehntop, Kevin D., Seo, Mi Sook, De Hont, Raymond F., Stubna, Audria, Halfen, Jason A., Münck, Eckard, Nam, Wonwoo, Que, Lawrence
Format: Artigo
Idioma:Inglês
Publicat: 2010
Matèries:
Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3049993/
https://ncbi.nlm.nih.gov/pubmed/21070030
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1045428
Etiquetes: Afegir etiqueta
Sense etiquetes, Sigues el primer a etiquetar aquest registre!

Ítems similars