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Hydrocarbon formation in the reductive cleavage of hydroperoxides by cytochrome P-450.
Evidence is presented that cytochrome P-450 catalyzes the reductive cleavage of hydroperoxides. For example, in a reconstituted system containing rabbit liver microsomal P-450 form 2, NADPH-cytochrome P-450 reductase, and NADPH, cumyl hydroperoxide yields acetophenone and methane, but no cumyl alcoh...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
1987
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC304388/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/3103131/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.84.5.1172 |
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