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Hydrocarbon formation in the reductive cleavage of hydroperoxides by cytochrome P-450.

Evidence is presented that cytochrome P-450 catalyzes the reductive cleavage of hydroperoxides. For example, in a reconstituted system containing rabbit liver microsomal P-450 form 2, NADPH-cytochrome P-450 reductase, and NADPH, cumyl hydroperoxide yields acetophenone and methane, but no cumyl alcoh...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Vaz, A D, Coon, M J
Format: Artigo
Sprache:Inglês
Veröffentlicht: 1987
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC304388/
https://ncbi.nlm.nih.gov/pubmed/3103131
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