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Hydrocarbon formation in the reductive cleavage of hydroperoxides by cytochrome P-450.

Evidence is presented that cytochrome P-450 catalyzes the reductive cleavage of hydroperoxides. For example, in a reconstituted system containing rabbit liver microsomal P-450 form 2, NADPH-cytochrome P-450 reductase, and NADPH, cumyl hydroperoxide yields acetophenone and methane, but no cumyl alcoh...

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書誌詳細
出版年:Proc Natl Acad Sci U S A
主要な著者: Vaz, A D, Coon, M J
フォーマット: Artigo
言語:Inglês
出版事項: National Academy of Sciences 1987
主題:
オンライン・アクセス:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC304388/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/3103131/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.84.5.1172
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