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Hydrocarbon formation in the reductive cleavage of hydroperoxides by cytochrome P-450.

Evidence is presented that cytochrome P-450 catalyzes the reductive cleavage of hydroperoxides. For example, in a reconstituted system containing rabbit liver microsomal P-450 form 2, NADPH-cytochrome P-450 reductase, and NADPH, cumyl hydroperoxide yields acetophenone and methane, but no cumyl alcoh...

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Main Authors: Vaz, A D, Coon, M J
格式: Artigo
語言:Inglês
出版: 1987
主題:
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC304388/
https://ncbi.nlm.nih.gov/pubmed/3103131
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