Catalysis by cytochrome P-450 of an oxidative reaction in xenobiotic aldehyde metabolism: deformylation with olefin formation.

As we have briefly described elsewhere, cytochrome P-450 catalyzes the oxidative deformylation of cyclohexane carboxaldehyde to yield cyclohexene and formic acid in a reaction believed to involve a peroxyhemiacetal-like adduct formed between the substrate and molecular oxygen-derived hydrogen peroxi...

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Veröffentlicht in:	Proc Natl Acad Sci U S A
Hauptverfasser:	Roberts, E S, Vaz, A D, Coon, M J
Format:	Artigo
Sprache:	Inglês
Veröffentlicht:	National Academy of Sciences 1991
Schlagworte:	Research Article
Online-Zugang:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC52631/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/1924356/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.88.20.8963
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