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Highly Enantioselective Mannich Reactions with α-Aryl Silyl Ketene Acetals and Imines
[Image: see text] Mannich reactions with chiral silicon Lewis acid-activated acylhydrazones and α-aryl silyl ketene acetals and α-aryl, α-alkyl silyl ketene imines proceed efficiently and with good to excellent levels of both diastereoselectivity and enantioselectivity. The reactions provide access...
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| Auteurs principaux: | , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2011
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3042282/ https://ncbi.nlm.nih.gov/pubmed/21235253 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol103096u |
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