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Asymmetric Cooperative Catalysis of Strong Brønsted Acid-Promoted Reactions Using Chiral Ureas
Cationic organic intermediates participate in a wide variety of useful synthetic transformations, but their high reactivity can render selectivity in competing pathways difficult to control. We describe a strategy for inducing enantioselectivity in reactions of protio-iminium ions, wherein a chiral...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2010
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2993568/ https://ncbi.nlm.nih.gov/pubmed/20167783 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1182826 |
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