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Bifunctional Asymmetric Catalysis: Amplification of Brønsted Basicity Can Orthogonally Increase the Reactivity of a Chiral Brønsted Acid
[Image: see text] The reactivity of a series of symmetrical chiral Brønsted acids (polar ionic hydrogen bond donors) follows the counterintuitive trend wherein the more Brønsted basic member is a more effective catalyst for the aza-Henry (nitro-Mannich) reaction. This new design element leads to a s...
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| Hlavní autoři: | , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2010
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2838452/ https://ncbi.nlm.nih.gov/pubmed/20151644 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja908814h |
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