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Transition State Analysis of Enantioselective Brønsted Base Catalysis by Chiral Cyclopropenimines
[Image: see text] Experimental (13)C kinetic isotope effects have been used to interrogate the rate-limiting step of the Michael addition of glycinate imines to benzyl acrylate catalyzed by a chiral 2,3-bis(dicyclohexylamino) cyclopropenimine catalyst. The reaction is found to proceed via rate-limit...
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| 出版年: | J Am Chem Soc |
|---|---|
| 主要な著者: | , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
American Chemical
Society
2014
|
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4230825/ https://ncbi.nlm.nih.gov/pubmed/25029194 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja504532d |
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