ロード中...

Transition State Analysis of Enantioselective Brønsted Base Catalysis by Chiral Cyclopropenimines

[Image: see text] Experimental (13)C kinetic isotope effects have been used to interrogate the rate-limiting step of the Michael addition of glycinate imines to benzyl acrylate catalyzed by a chiral 2,3-bis(dicyclohexylamino) cyclopropenimine catalyst. The reaction is found to proceed via rate-limit...

詳細記述

保存先:
書誌詳細
出版年:J Am Chem Soc
主要な著者: Bandar, Jeffrey S., Sauer, Gregory S., Wulff, William D., Lambert, Tristan H., Vetticatt, Mathew J.
フォーマット: Artigo
言語:Inglês
出版事項: American Chemical Society 2014
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC4230825/
https://ncbi.nlm.nih.gov/pubmed/25029194
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja504532d
タグ: タグ追加
タグなし, このレコードへの初めてのタグを付けませんか!