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Synchrotron Radiation Provides a Plausible Explanation for the Generation of a Free Radical Adduct of Thioxolone in Mutant Carbonic Anhydrase II

Thioxolone acts as a prodrug in the presence of carbonic anhydrase II (CA II), whereby the molecule is cleaved by thioester hydrolysis to the carbonic anhydrase inhibitor, 4-mercaptobenzene-1,3-diol (TH0). Thioxolone was soaked into the proton transfer mutant H64A of CA II in an effort to capture a...

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Main Authors: Sippel, Katherine H., Genis, Caroli, Govindasamy, Lakshmanan, Agbandje-McKenna, Mavis, Kiddle, James J., Tripp, Brian C., McKenna, Robert
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2010
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2957018/
https://ncbi.nlm.nih.gov/pubmed/20976122
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jz100954h
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