Yüklüyor......

Probing active site geometry using high pressure and secondary isotope effects in an enzyme-catalysed ‘deep’ H-tunnelling reaction

We report the first study of the effects of hydrostatic pressure on α-2° KIEs for an enzyme-catalysed H-transfer reaction that occurs by ‘deep’ tunnelling. High pressure causes a significant decrease in the observed α-2° KIE on the pre-steady-state hydride transfer from NADH to FMN in the flavoprote...

Ful tanımlama

Kaydedildi:
Detaylı Bibliyografya
Asıl Yazarlar: Hay, Sam, Pudney, Christopher R., Sutcliffe, Michael J., Scrutton, Nigel S.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2010
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC2948560/
https://ncbi.nlm.nih.gov/pubmed/20890464
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/poc.1653
Etiketler: Etiketle
Etiket eklenmemiş, İlk siz ekleyin!