Hydrogen tunnelling in enzyme-catalysed H-transfer reactions: flavoprotein and quinoprotein systems

It is now widely accepted that enzyme-catalysed C–H bond breakage occurs by quantum mechanical tunnelling. This paradigm shift in the conceptual framework for these reactions away from semi-classical transition state theory (TST, i.e. including zero-point energy, but with no tunnelling correction) h...

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Autori principali: Sutcliffe, Michael J, Masgrau, Laura, Roujeinikova, Anna, Johannissen, Linus O, Hothi, Parvinder, Basran, Jaswir, Ranaghan, Kara E, Mulholland, Adrian J, Leys, David, Scrutton, Nigel S
Natura: Artigo
Lingua:Inglês
Pubblicazione: The Royal Society 2006
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Research Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC1647315/
https://ncbi.nlm.nih.gov/pubmed/16873125
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rstb.2006.1878
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