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Unusual origins of isotope effects in enzyme-catalysed reactions
High hydrostatic pressure is a neglected tool for probing the origins of isotope effects. In chemical reactions, normal primary deuterium isotope effects (DIEs) arising solely from differences in zero point energies are unaffected by pressure; but some anomalous isotope effects in which hydrogen tun...
Bewaard in:
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| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
The Royal Society
2006
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1647306/ https://ncbi.nlm.nih.gov/pubmed/16873122 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rstb.2006.1875 |
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