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Does the pressure dependence of kinetic isotope effects report usefully on dynamics in enzyme H‐transfer reactions?
The temperature dependence of kinetic isotope effects (KIEs) has emerged as the main experimental probe of enzymatic H‐transfer by quantum tunnelling. Implicit in the interpretation is a presumed role for dynamic coupling of H‐transfer chemistry to the protein environment, the so‐called ‘promoting m...
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| Опубликовано в: : | FEBS J |
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| Главные авторы: | , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
John Wiley and Sons Inc.
2015
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4949571/ https://ncbi.nlm.nih.gov/pubmed/25581554 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1111/febs.13193 |
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