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Spiroborate esters in the borane-mediated asymmetric synthesis of pyridyl and related heterocyclic alcohols

The effectiveness of several spiroborate ester catalysts was investigated in the asymmetric borane reduction of 2-, 3-, 4-acetylpyridines under different reaction conditions. Highly enantiomerically enriched 1-(2-, 3- and 4-pyridyl)ethanols and 1-(heterocyclic)ethanols were obtained using 1 to 10% c...

תיאור מלא

שמור ב:
מידע ביבליוגרפי
Main Authors: Stepanenko, Viatcheslav, De Jesús, Melvin, Correa, Wildeliz, Guzmán, Irisbel, Vázquez, Cindybeth, Ortiz, Lymaris, Ortiz-Marciales, Margarita
פורמט: Artigo
שפה:Inglês
יצא לאור: 2007
נושאים:
גישה מקוונת:https://ncbi.nlm.nih.gov/pmc/articles/PMC2948488/
https://ncbi.nlm.nih.gov/pubmed/20890455
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetasy.2007.10.044
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