Asymmetric Synthesis of Primary Amines via the Spiroborate-Catalyzed Borane Reduction of Oxime Ethers

[Image: see text] The enantioselective borane reduction of O-benzyloxime ethers to primary amines was studied under catalytic conditions using the spiroborate esters 5 – 10 derived from non-racemic 1,2-amino alcohols and ethylene glycol. Effective catalytic conditions were achieved using only 10% of...

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Main Authors: Huang, Xiaogen, Ortiz-Marciales, Margarita, Huang, Kun, Stepanenko, Viatcheslav, Merced, Francisco G., Ayala, Angel M., Correa, Wildeliz, De Jesús, Melvin
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2571073/
https://ncbi.nlm.nih.gov/pubmed/17397177
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0704791
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