Enantioselective Reduction of Prochiral Ketones using Spiroborate Esters as Catalysts

Novel spiroborate esters derived nonracemic 1,2-aminoalcohols and ethylene glycol are reported as highly effective catalysts for the asymmetric borane reduction of a variety of prochiral ketones with borane-dimethyl sulfide complex at room temperature. Optically active alcohols were obtained in exce...

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Main Authors: Stepanenko, Viatcheslav, De Jesus, Melvin, Correa, Wildeliz, Guzman, Irisbel, Vazquez, Cindybeth, de la Cruz, Wilanet, Ortiz-Marciales, Margarita, Barnes, Charles L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2701200/
https://ncbi.nlm.nih.gov/pubmed/19554205
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2007.06.086
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