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Highly Efficient Diastereoselective Reduction of α-Fluoroimines
[Image: see text] A highly selective reduction of α-fluoroimines to the corresponding β-fluoroamines has been developed utilizing trichlorosilane as the reductant. The key aspect of this reaction is the ability of fluorine and nitrogen to activate organosilanes leading to high diastereoselectivity (...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2929650/ https://ncbi.nlm.nih.gov/pubmed/20408600 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100647b |
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